The PAOs are manufacturered in two types and in various molecular weights. The types are polar and non-polar. With the use of polar PAOs, the film is attracted to the parts like a magnet. Sounds great-right? Wrong, because the film strength is so strong, the additive package can't get in to do its job and wear is accelerated. Mobil will use an alkylated napthalene to cut the film strenght and provide for a binder to mix the add packs. PAOs do not supoort the additives and will not mix with them without a binder. The other type of PAO is the non-polar type. It is not attracted to the parts and will run off of the internals of the engine and back to the pan. Tackifiers are used to attempt to cure the issue. On long runs between changes, don't count the tackifiers to work as good as when new. Both types have issues. Winter wear metals using PAOs will be 50% or more greater than that of a regular dino base oil due mostly to corrosion. PAOs of any kind will have more favorable flow at extreme cold temps like -35F. If you have that kind of cold start up temps, you need to be using a PAO basestocked synthetic oil. A Gp III dino synthetic will not be as good such as Castrols Syntec.
Concerning the percentage of synthetic to make a blend. It is industry driven and 10% is considered a minimum. The most percentage of Gp III basestock would be Phillips Trop Artic at 60% synthetic Gp III.
Extending oil changes to 5000 miles and certain engines to 7500 is not really a problem anymore. The oils have improved dramatically in the last ten years alone. Engine developement has made great strides as well. The lean burn engines of today with their management systems are far, far cleaner than the engines of the early 90's. Many years ago when we used leaded gas, the analysis would come back for lead at like 350 ppms and iron of 400+ and this was for a 3000 miles OCI. Iron today for most Triton engines at 5000 miles is just barely double digit like 20 or less. Some of the clean burning is also attributable to the fuels we use today. It's on the drawing board, oil changes by dealers only at 50,000 miles. First reports are promising. Filters will not only filter but also have time release additive packages in them. The ones I have seen are about the size of a half gallon can and filter to 3 microns. That's quite an accomplishment.